Diethyl 2-[(N-benzyl-N-methyl­amino)(phen­yl)meth­yl]propane­dioate

نویسندگان

  • Ihssan Meskini
  • Maria Daoudi
  • Jean-Claude Daran
  • Hafid Zouihri
  • Taibi Ben Hadda
چکیده

In the title compound, C(22)H(27)NO(4), the mean planes of the two benzene rings form a dihedral angle of 73.54 (13)°. One of the methyl groups is disordered over two sites, with site occupation factors of 0.47 (15) and 0.53 (15). The crystal packing is controlled by van der Waals forces and a possible C-H⋯O inter-action, forming a chain running parallel to the a axis.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Diethyl 2-[phen­yl(pyrazol-1-yl)meth­yl]propane­dioate

There are two independent mol-ecules in the asymmetric unit of the title compound, C(17)H(20)N(2)O(4), which differ slightly in the orientation of the phenyl ring and carbonyl groups with respect to the pyrazole unit. In the first mol-ecule, the dihedral angle between the phenyl and pyrazole rings is 68.99 (13)° while the two carbonyl groups make a dihedral angle of 72.1 (4)°. The corresponding...

متن کامل

Diethyl 2-[(3,5-dimethyl-1H-pyrazol-1-yl)(4-meth­oxy­phen­yl)meth­yl]propane­dioate

The title compound, C(20)H(26)N(2)O(5), was prepared in good yield (76%) through condensation of diethyl (4-meth-oxy-benz-yl)propane-dioate with 3,5-dimethyl-1H-pyrazole. The dihedral between the benzene and pyrazole rings is 83.96 (10)°. The crystal packing is stabilized by a C-H⋯O inter-action, which links the mol-ecules into centrosymmetric dimers.

متن کامل

{2-[(Dimethyl­amino)­meth­yl]phen­yl}bis­(4-methyl­phen­yl)bis­muthane

The title compound, [Bi(C(7)H(7))(2)(C(9)H(12)N)], was obtained by treating chlorodi(p-tol-yl)bis-muthane with o-lithio-N,N-dimethyl-benzyl-amine. An intra-molecular Bi⋯N nonbonding inter-action is observed in the distorted trigonal triaryl-bis-muth coordination of the title compound.

متن کامل

Bis[2-({[2-(methyl­sulfan­yl)phen­yl]imino}­meth­yl)phenolato-κ2 N,O]zinc chloro­form disolvate

The monomeric title complex, [Zn(C14H12NOS)2]·2CHCl3 or L2Zn·2CHCl3, where L is the 2-({[2-(methyl-sulfan-yl)phen-yl]imino}-meth-yl)phenolate anion, may be obtained by the reaction of LZnEt with benzyl alcohol or by the reaction of two equivalents of LH with ZnEt2 in tetra-hydro-furan. The Zn atom, located on a twofold axis, is four-coordinated in a distorted tetra-hedral geometry by two O atom...

متن کامل

Diethyl [(4-nitrobenzamido)(phen­yl)meth­yl]phospho­nate

In the title compound, C18H21N2O6P, the dihedral angle between the benzene and phenyl rings is 85.1 (2)°. In the crystal, mol-ecules are linked via pairs of N-H⋯O(=P) hydrogen bonds, forming inversion dimers with graph-set notation R 2 (2)(10). One of the ethyl groups is disordered over two sets of sites, with occupancies 0.746 (11) and 0.254 (11).

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:

دوره 66  شماره 

صفحات  -

تاریخ انتشار 2010